Solubility Equilibria of Sparingly Soluble Salts

Solubility Equilibria of Sparingly Soluble Salts

The solubility depends on a number of factors important amongst which are the lattice enthalpy of the salt and the solvation enthalpy of the ions in a solution. For a salt to dissolve in a solvent the strong forces of attraction between its ions (lattice enthalpy) must be overcome by the ion-solvent interactions. The solvation Read more about Solubility Equilibria of Sparingly Soluble Salts[…]

Chemistry

Relationship between equilibrium constant K, reaction quotient Q and Gibbs energy G

We know that if,  ΔG is negative, then the reaction is spontaneous and proceeds in the forward direction. ΔG is positive, then reaction is considered non-spontaneous. Instead, as reverse reaction would take place  ΔG is 0, reaction has achieved equilibrium; at this point, there is no longer any free energy left to drive the reaction. Read more about Relationship between equilibrium constant K, reaction quotient Q and Gibbs energy G[…]

Chemistry

Gibbs Energy change and Equilibrium

Free Energy Change (ΔG):  The two thermodynamic quantities which affect the spontaneity of a reaction are enthalpy (H) and entropy (S). The free energy is the amount of work that a thermodynamic system can perform The free energy of a substance such as its enthalpy or entropy is a characteristic property of the substance. In any reaction, the change in free Read more about Gibbs Energy change and Equilibrium[…]